Campus Units

Mechanical Engineering, Agricultural and Biosystems Engineering, Chemical and Biological Engineering, Bioeconomy Institute (BEI)

Document Type

Article

Publication Version

Accepted Manuscript

Publication Date

7-22-2020

Journal or Book Title

Reaction Chemistry and Engineering

DOI

10.1039/D0RE00192A

Abstract

Large-scale production of biofuels and chemicals will require cost-effective, sustainable, and rapid deconstruction of waste biomass into its constituent sugars. Here, we introduce a novel two-step liquefaction process for producing fermentable sugars from hardwood biomass using a mixture of tetrahydrofuran (THF), water and dilute sulfuric acid. THF promotes acid-catalyzed solubilization of lignin and hemicellulose in biomass achieving 61% lignin extraction and 64% xylose recovery in a mild pretreatment step. The pretreatment opens the structure of biomass through delignification and produces a cellulose-rich biomass, which is readily solubilized at low temperature giving 65% total sugar yields in a subsequent liquefaction process employing the same solvent mixture. This process achieves competitive sugar yields at high volumetric productivity compared to conventional saccharification methods. THF, which can be derived from renewable resources, has several benefits as solvent including ease of recovery from the sugar solution and relatively low toxicity and cost.

Comments

This is a manuscript of an article published as Ghosh, Arpa, Martin Haverly, Jake Lindstrom, Patrick A. Johnston, and Robert C. Brown. "Tetrahydrofuran-based two-step solvent liquefaction process for production of lignocellulosic sugars." Reaction Chemistry & Engineering (2020). DOI: 10.1039/D0RE00192A. Posted with permission.

Creative Commons License

Creative Commons Attribution 3.0 License
This work is licensed under a Creative Commons Attribution 3.0 License.

Copyright Owner

The Author(s)

Language

en

File Format

application/pdf

Published Version

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