Strains and Polarization During Antiferroelectric–Ferroelectric Phase Switching in Pb0.99Nb0.02[(Zr0.57Sn0.43)1−yTiy]0.98O3 Ceramics

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2011-01-01
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Frederick, Joshua
Tan, Xiaoli
Jo, Wook
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Tan, Xiaoli
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Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
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Abstract

The electric field-induced antiferroelectric-to-ferroelectric phase transition is investigated through detailed measurements of electric polarization P, longitudinal strain x33, and transverse strain x11 developed under applied electric fields in a series of Pb0.99Nb0.02[(Zr0.57Sn0.43)1−yTiy]0.98O3 ceramics with compositions close to the antiferroelectric/ferroelectric phase boundary. It is found that the volume expansion, expressed as (x33+2x11), at the antiferroelectric-to-ferroelectric phase transition remains ∼0.4% regardless of the composition in the range of 0.060≤y≤0.075. However, the induced ferroelectric phase in compositions y≥0.069 becomes metastable and the ferroelectric-to-antiferroelectric phase transition does not occur during the unloading of the applied field. This reverse phase transition occurs partially when electric fields with reversed polarity are applied. As a consequence, the switchable mechanical strains in compositions y≥0.069 are significantly reduced as y (Ti content) increases even though the switchable polarization remains at a high value.

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This is the peer reviewed version of the following article: Journal of the American Ceramic Society 94, 1149-1155 (2011). DOI: 10.1111/j.1551-2916.2010.04194.x which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1111/j.1551-2916.2010.04194.x/full.

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Sat Jan 01 00:00:00 UTC 2011
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