Document Type
Article
Publication Version
Published Version
Publication Date
2014
Journal or Book Title
Inorganic Chemistry
Volume
53
Issue
17
First Page
9027
Last Page
9035
DOI
10.1021/ic500979p
Abstract
In this paper, we report on the syntheses, structures, and characterization of four molten salts containing imidazolium cations and europium(III)- or terbium(III)-centered complex anions. In the complex anions, the lanthanide centers are wrapped by four pseudodiketonate anionic ligands, which prevent them from contacting with high-frequency oscillators and allow them to show intense characteristic europium(III) or terbium(III) emission, small line widths, high color purity, high quantum yields (30−49%), and long decay times (>2 ms).
Copyright Owner
American Chemical Society
Copyright Date
2014
Language
en
File Format
application/pdf
Recommended Citation
Tang, Si-Fu; Lorbeer, Chantel; Wang, Xinjiao; Ghosh, Pushpal; and Mudring, Anja V., "Highly Luminescent Salts Containing Well-Shielded Lanthanide-Centered Complex Anions and Bulky Imidazolium Countercations" (2014). Materials Science and Engineering Publications. 204.
https://lib.dr.iastate.edu/mse_pubs/204
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Comments
Reprinted with permission from Inorg. Chem., 2014, 53 (17), pp 9027–9035. Copyright 2014 American Chemical Society.