Campus Units
Materials Science and Engineering, Ames Laboratory
Document Type
Article
Publication Version
Accepted Manuscript
Publication Date
2-15-2021
Journal or Book Title
Journal of Alloys and Compounds
Volume
854
First Page
157064
DOI
10.1016/j.jallcom.2020.157064
Abstract
Thermodynamics of the Pt–Sn system is revisited with attention to phase equilibria involving PtSn4, a topological quantum material with interesting physical properties. The phase relationship in the Sn-rich region of the Pt–Sn binary system was investigated by a combination of differential scanning calorimetry and equilibration experiments. Based on the present experiments and a critical evaluation of the available thermodynamic and phase diagram data reported in the literature, thermodynamic assessments of the entire Pt–Sn system were performed using the CALPHAD approach. Two sets of thermodynamic parameters were optimized, where the liquid phase was described using the Bragg-Williams random mixing model and the associate solution model, respectively. The modeling results are compared with the reliable experimental data and are shown to provide good representations of phase equilibria and thermodynamic properties in this system.
Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-No Derivative Works 4.0 International License.
Copyright Owner
Elsevier B.V.
Copyright Date
2020
Language
en
File Format
application/pdf
Recommended Citation
Cui, Senlin; Lynn, Matthew J.; and Napolitano, Ralph E., "Experimental investigation and thermodynamic modeling of the binary Pt–Sn system" (2021). Materials Science and Engineering Publications. 388.
https://lib.dr.iastate.edu/mse_pubs/388
Comments
This is a manuscript of an article published as Cui, Senlin, Matthew Lynn, and Ralph E. Napolitano. "Experimental investigation and thermodynamic modeling of the binary Pt–Sn system." Journal of Alloys and Compounds 854 (2021): 157064. DOI: 10.1016/j.jallcom.2020.157064. Posted with permission.