Campus Units

Materials Science and Engineering, Industrial and Manufacturing Systems Engineering, Ames Laboratory

Document Type

Article

Publication Version

Submitted Manuscript

Publication Date

11-13-2020

Journal or Book Title

Nano Letters

DOI

10.1021/acs.nanolett.0c03641

Abstract

Multifunctional surfactants hold great potentials in catalysis, separation, and biomedicine. Highly active plasmonic-magnetic nanosurfactants are developed through a novel acid activation treatment of Au–Fe3O4 dumbbell nanocrystals. The activation step significantly boosts nanosurfactant surface energy and enables the strong adsorption at interfaces, which reduces the interfacial energy one order of magnitude. Mediated through the adsorption at the emulsion interfaces, the nanosurfactants are further constructed into free-standing hierarchical structures, including capsules, inverse capsules, and two-dimensional sheets. The nanosurfactant orientation and assembly structures follow the same packing parameter principles of surfactant molecules. Furthermore, nanosurfactants demonstrate the capability to disperse and encapsulate homogeneous nanoparticles and small molecules without adding any molecular surfactants. The assembled structures are responsive to external magnetic field, and triggered release is achieved using an infrared laser by taking advantage of the enhanced surface plasmon resonance of nanosurfactant assemblies. Solvent and pH changes are also utilized to achieve the cargo release.

Comments

This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Nano Letters, copyright © American Chemical Society after peer review. To access the final edited and published work see DOI: 10.1021/acs.nanolett.0c03641. Posted with permission.

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

2020-JiangShan-ActivationAssembly-SI.pdf (2133 kB)
Supporting Information

Published Version

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