Document Type

Article

Publication Date

5-3-2004

Journal or Book Title

Inorganic Chemistry

Volume

43

Issue

9

First Page

2773

Last Page

2775

DOI

10.1021/ic035454m

Abstract

The thioborate phase Ba7(BS3)4S crystallizes in the monoclinic space group C2/c (No. 15) with a = 10.1750(15) Å, b = 23.970(4) Å, c = 10.1692(15) Å, β = 90.095(2)°, and Z = 4. The structure consists of isolated trigonal planar (BS3)3- anions, and isolated S2- anions and Ba2+ cations. The vibrational modes of the isolated (BS3)3- units were measured from Raman scattering and IR absorption spectra, and the frequencies agree very well with those found for similar orthothioborate phases.

Comments

Reprinted with permission from Inorganic Chemistry 43 (2004): 2773–2775, doi:10.1021/ic035454m. Copyright 2004 American Chemistry

Copyright Owner

American Chemical Society

Language

en

File Format

application/pdf

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