Document Type
Article
Publication Date
2-25-2002
Journal or Book Title
Inorganic Chemistry
Volume
41
Issue
4
First Page
622
Last Page
624
DOI
10.1021/ic0155737
Abstract
A new method to prepare polycrystalline meta-thioboric acid (c-HBS2) has been developed and reported. HBS2 was obtained as a vapor condensate by reacting H2S with B2S3 in the vapor phase, and the optimal conditions for this reaction are reported. The X-ray and spectroscopic characterization suggest that the structure of thioboric acid is monoclinic and made up of hexagonal rings formed by trimer units, (HBS2)3. The present preparation route is facile, faster than other wet routes of thiolysis, and the reaction requires much lower temperatures, thus avoiding contamination by reactor materials.
Copyright Owner
American Chemical Society
Copyright Date
2002
Language
en
File Format
application/pdf
Recommended Citation
Karthikeyan, Annamalai; Martindale, Chad A.; and Martin, Steve W., "New Method to Prepare Polycrystalline Meta-thioboric Acid, (HBS2)3" (2002). Materials Science and Engineering Publications. 72.
https://lib.dr.iastate.edu/mse_pubs/72
Comments
Reprinted with permission from Inorganic Chemistry 41 (2002): 622–624, doi:10.1021/ic0155737. Copyright 2002 American Chemical Society.