Crystallography and magnetism of the heavy-fermion compound YbBiPt

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1994-10-01
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Robinson, R. A.
Purwanto, A.
Kohgi, M.
Canfield, Paul
Kamiyama, T.
Ishigaki, T.
Lynn, J. W.
Erwin, R.
Peterson, E.
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Canfield, Paul
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Physics and Astronomy
Physics and astronomy are basic natural sciences which attempt to describe and provide an understanding of both our world and our universe. Physics serves as the underpinning of many different disciplines including the other natural sciences and technological areas.
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Ames National LaboratoryPhysics and Astronomy
Abstract

The super-heavy-fermion compound YbBiPt has the largest known linear specific-heat coefficient γ=8 J mol−1 K−2, and the source of this enormous ‘‘electronic’’ specific heat is of great current interest. Here we describe neutron-diffraction studies that indicate its previously reported crystallographic structure to be incorrect. We find that the Pt atom is on the unique site and can be thought of as an interstitial in a fictitious rock-salt structure YbBi, which can in turn be thought of as an ordered form of elemental bismuth. We find no evidence of disorder between sites, occupancy on the nominally vacant site, nor for any tetragonal or rhombohedral distortions or displacements. Furthermore, any ordered magnetic moment at low temperature must be less than 0.25μB. The sample contains 8.1 wt. % elemental Bi, and if this is typical of other samples, the previously published values for molar susceptibilities and specific heats should be scaled up by this amount to obtain the intrinsic properties of YbBiPt alone.

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This article is published as Robinson, R. A., A. Purwanto, M. Kohgi, P. C. Canfield, T. Kamiyama, T. Ishigaki, J. W. Lynn, R. Erwin, E. Peterson, and R. Movshovich. "Crystallography and magnetism of the heavy-fermion compound YbBiPt." Physical Review B 50, no. 13 (1994): 9595. DOI: 10.1103/PhysRevB.50.9595.

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