Bridgehead approaches toward polycyclic alkaloids
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The Department of Chemistry seeks to provide students with a foundation in the fundamentals and application of chemical theories and processes of the lab. Thus prepared they me pursue careers as teachers, industry supervisors, or research chemists in a variety of domains (governmental, academic, etc).
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The Department of Chemistry was founded in 1880.
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1880-present
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- College of Liberal Arts and Sciences (parent college)
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Abstract
Relatively little attention has been given to the use of bridgehead radicals in synthetic organic chemistry. In an effort to exploit the potential of this intermediate, a study has been undertaken to show the usefulness of these intermediates for the preparation of complex systems. As a result of this study, it has been shown that bridgehead radicals can be prepared in highly functionalized systems. The radical adducts from these reactions have been used for the preparation of potential intermediates of the polycyclic diterpene alkaloids.