Magnetic, caloric and crystallographic properties of Dy5(Si[subscript x]Ge1-[subscript x])4 alloys

Thumbnail Image
Date
2002-01-01
Authors
Ivchenko, Vitaliy
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Altmetrics
Authors
Research Projects
Organizational Units
Organizational Unit
Materials Science and Engineering
Materials engineers create new materials and improve existing materials. Everything is limited by the materials that are used to produce it. Materials engineers understand the relationship between the properties of a material and its internal structure — from the macro level down to the atomic level. The better the materials, the better the end result — it’s as simple as that.
Journal Issue
Is Version Of
Versions
Series
Department
Materials Science and Engineering
Abstract

A study of a series of Dy5(Si[Subscript x]Ge[Subscript 1-x])4 alloys using dc and ac magnetic susceptibility, magnetization, heat capacity, and x-ray powder diffraction techniques revealed that the variation of the magnetic properties and crystal structures with composition is similar to that observed in the Gd5(Si[Subscript x]Ge[Subscript 1-x])4 system, except that the magnetic ordering temperatures are lower. The magnetic phase transition temperatures vary from [Difference symbol] 46K (Dy5Ge4) to [Difference symbol] 137K (Dy5Si4). The intermediate ternary phase Dy5Si3Ge undergoes a first order magnetic phase transition at [Difference symbol] 65K. The value of magnetic entropy change for this composition is quite large (-34J/kgK for magnetic field change from 0 to 50kOe), compared to the values for the two end members (-7 J/kgK for Dy5Ge4 and -12.5J/kgK for Dy5Si4). The magnetization and ac susceptibility measurements showed that alloys with monoclinic crystal structure have a non-collinear ordering of the magnetic moments at low temperatures. The alloy Dy5Si3Ge appears to exhibit a spin-glass transformation below the magnetic phase transition at 65K. Also a series of critical fields are observed at low temperature during magnetization vs magnetic field measurements in all of the Dy5(Si[Subscript x]Ge[Subscript 1-x])4 alloys regardless type of crystal structure. The Dy5(Si[Subscript x]Ge[Subscript 1-x])4 alloys, where 0.67[Less than or equal to]x[Less than or equal to]l, may be useful magnetic refrigerant materials in the [Difference symbol]50 to [Difference symbol]160K temperature range.

Comments
Description
Keywords
Citation
Source
Copyright
Tue Jan 01 00:00:00 UTC 2002